Get A Novel Heme-Thiolate Peroxygenase AaeAPO and Its PDF

By Xiaoshi Wang

ISBN-10: 3319032356

ISBN-13: 9783319032351

during this thesis, Xiaoshi Wang investigates the functionality and mechanism of a newly stumbled on heme-thiolate peroxygenase, AaeAPO. This enzyme category comes from Agrocybe aegerita and is utilized in the conversion of inert hydrocarbons to alcohols. Xiaoshi's paintings specializes in an extracellular P450 enzyme which isn't constrained in its balance and absence of solubility and consequently is suitable for common business use. the writer demonstrates that the peroxygenase catalyzes a variety of reactions. every now and then the writer even describes very tough changes in molecules which are hugely inert. Her designated investigations supply a mechanistic framework for a way the peroxygenase catalyzes the sort of huge variety of reactions. an enormous spotlight of this thesis is the id of key short-lived intermediates within the catalytic cycle of the peroxygenase, utilizing swift kinetic and spectroscopic tools, in addition to the elucidation of the thermodynamic homes of those high-energy intermediates. This paintings provides new perception into a major classification of enzymes.

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A Novel Heme-Thiolate Peroxygenase AaeAPO and Its Implications for C-H Activation Chemistry (Springer Theses) by Xiaoshi Wang

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